McCann, Malachy and Murphy, Eamonn and Cardin, Christine and Convery, Maire (1993) Synthesis and properties of tetra-μ-acetatodiruthenium(II,III) phenylphosphinate and phenylphosphonate complexes: X-ray crystal structures of [Ru2(μ-O2CCH3)4(HPhPO2)2]H and [Ru2(μ-O2CCH3)4(PhPO3H)2]H·H2O. Polyhedron, 12 (14). pp. 1725-1731. ISSN 0277-5387

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Abstract

Phenylphosphinic acid (HPhPO2H) and phenylphosphonic acid (PhPO3H2) react with a methanolic solution of [Rui(µ-O2CCH3MO2CCH3h]H · 0.7H2O at room tempera­ture to give [Rui(µ-O2CCH3MHPhPO2) 2]H (1) and [Ruiµ-O2CCH3)4 (PhPO3H)2]H · H2O (2), respectively. The X-ray crystal structures of 1 and 2 each show the Ru-Ru core to be ligated by four bridging bidentate acetate ligands [Ru-Ru distances: 1 = 2.272( I) A; 2 = 2.267(2) A.) and two axial phenylphosphinate and phenylphosphonate ligands, respec­tively. In each complex the individual bimetallic molecules are linked together by a hydrogen ion which bridges the oxygen atoms of neighbouring axial ligands. In 2 the water molecule is also hydrogen-bonded to one of the axial phenylphosphonate groups. Spectroscopic, magnetic and cyclic voltammetric data for the complexes are given.

Item Type:	Article
Keywords:	Synthesis; properties;tetra-μ-acetatodiruthenium(II,III); phenylphosphinate; phenylphosphonate complexes; X-ray; crystal; structures; [Ru2(μ-O2CCH3)4(HPhPO2)2]H; [Ru2(μ-O2CCH3)4(PhPO3H)2]H·H2O;
Academic Unit:	Faculty of Science and Engineering > Chemistry
Item ID:	14561
Identification Number:	https://doi.org/10.1016/S0277-5387(00)84604-5
Depositing User:	Dr. Malachy McCann
Date Deposited:	23 Jun 2021 14:27
Journal or Publication Title:	Polyhedron
Publisher:	Elsevier
Refereed:	Yes
URI:
Use Licence:	This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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