McKay, Alasdair I. and Krämer, Tobias and Rees, Nichollas H. and Thompson, Amber L. and Christensen, Kirsten E. and Macgregor, Stuart A. and Weller, Andrew S.
(2017)
Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4].
Organometallics, 36 (1).
pp. 22-25.
ISSN 0276-7333
Abstract
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
| Item Type: |
Article
|
| Keywords: |
Paraffins; Molecular rearrangement; Periodic DFT; Single crystal-to-single crystal reactions; Single crystals; |
| Academic Unit: |
Faculty of Science and Engineering > Chemistry |
| Item ID: |
11592 |
| Identification Number: |
https://doi.org/10.1021/acs.organomet.6b00645 |
| Depositing User: |
Tobias Kraemer
|
| Date Deposited: |
04 Nov 2019 14:42 |
| Journal or Publication Title: |
Organometallics |
| Publisher: |
American Chemical Society |
| Refereed: |
Yes |
| URI: |
|
| Use Licence: |
This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available
here |
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