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    Protonolysis of an α-Hydroxyl Ligand for the Generation of a PCcarbeneP Pincer Complex and Subsequent Reactivity Studies


    Sung, Simon and Joachim, Timothy and Krämer, Tobias and Young, Rowan D. (2017) Protonolysis of an α-Hydroxyl Ligand for the Generation of a PCcarbeneP Pincer Complex and Subsequent Reactivity Studies. Organometallics, 36 (16). pp. 3117-3124. ISSN 0276-7333

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    Abstract

    A rhodium α-hydroxylalkyl complex (1) reacts rapidly with Brookhart’s acid, [H(OEt2)2][B(3,5-(CF3)2-C6H3)4], to generate a cationic PCcarbeneP complex (2). Complex 2 can also be accessed from salt metathesis of an α-hydroxyalkyl hydrochlorido rhodium(III) complex (4) with Na[B(3,5-(CF3)2-C6H3)4]. The reactivity of compound 2 is explored through a series of reactions with various nucleophilic and electrophilic reagents.

    Item Type: Article
    Keywords: Carbene; Palladium; Rhodium; Iridium; Nickel; Molecular Structure; Metallacyclic Manganese; Stabilization; Chemistry, Organic; Ruthenium; C-H Activation; Chemistry, inorganic & nuclear;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 11594
    Identification Number: https://doi.org/10.1021/acs.organomet.7b00461
    Depositing User: Tobias Kraemer
    Date Deposited: 04 Nov 2019 15:02
    Journal or Publication Title: Organometallics
    Publisher: American Chemical Society
    Refereed: Yes
    URI:

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