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    (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand


    Ahmed, Muhib and Devereux, Michael and McKee, Vickie and McCann, Malachy and Rooney, Denise (2019) (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand. Acta Crystallographica. Section E, Crystallographic Communications, 75. pp. 1224-1227. ISSN 2056-9890

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    Abstract

    Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2·2CHCl3.

    Item Type: Article
    Keywords: crystal structure; diazo; phenanthroline; superconjugated ligand;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 12585
    Identification Number: https://doi.org/10.1107/S205698901900954X
    Depositing User: Dr. Denise Rooney
    Date Deposited: 23 Mar 2020 12:09
    Journal or Publication Title: Acta Crystallographica. Section E, Crystallographic Communications
    Publisher: International Union of Crystallography
    Refereed: Yes
    URI:

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