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    Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]


    McMahon, Suzanne and Rochford, Jonathan and Halpin, Yvonne and Manton, Jennifer C. and Harvey, Emma C. and Greetham, Gregory M. and Clark, Ian P. and Rooney, A. Denise and Long, Conor and Pryce, Mary T. (2014) Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]. Physical Chemistry Chemical Physics, 16. pp. 21230-21233. ISSN 1463-9076

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    Abstract

    Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

    Item Type: Article
    Keywords: Controlled CO release; photochemical; thermal; electrochemical; approaches; amino carbene complex; [(CO)5CrC(NC4H8)CH3];
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 7811
    Identification Number: https://doi.org/10.1039/c4cp03758h
    Depositing User: Dr. Denise Rooney
    Date Deposited: 25 Jan 2017 15:03
    Journal or Publication Title: Physical Chemistry Chemical Physics
    Publisher: Royal Society of Chemistry
    Refereed: Yes
    Funders: Irish Research Council, Science Foundation Ireland (SFI), Environmental Protection Agency (EPA)
    URI:

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