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Beaumont, Andrew J., Kiely, Christopher and Rooney, A. Denise (2001) Synthesis of novel chiral quaternary phosphonium fluorides: reagents for simple asymmetric nucleophilic fluorination reactions. Journal of Fluorine Chemistry, 108 (1). pp. 47-50. ISSN 0022-1139
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Abstract
The novel chiral quaternary salt (RP)-benzylmenthylmethylphenylphosphonium fluoride was synthesised. The compound was used in the asymmetric nucleophilic fluorination of 2-bromopropiophenone to give 2-fluoropropiophenone in a 35% yield with [α]D20=+1.94°.
| Item Type: | Article |
|---|---|
| Keywords: | Asymmetric; Nucleophilic; Fluorination; Chiral; Phosphonium; Fluoride; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7984 |
| Identification Number: | 10.1016/S0022-1139(00)00401-2 |
| Depositing User: | Dr. Denise Rooney |
| Date Deposited: | 01 Mar 2017 16:03 |
| Journal or Publication Title: | Journal of Fluorine Chemistry |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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