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    Redox control of meso-Zinc(II) ferrocenylporphyrin based fluorescence switches


    Rochford, Jonathan and Rooney, A. Denise and Pryce, Mary T. (2007) Redox control of meso-Zinc(II) ferrocenylporphyrin based fluorescence switches. Inorganic Chemistry, 46 (18). pp. 7247-7249. ISSN 0020-1669

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    Abstract

    The switching on and off of porphyrin fluorescence is achieved through the use of the ferrocene/ferrocenium redox couple. This approach makes use of the quenching of the porphyrin fluorescence by excited-state electron transfer from the ferrocene to the porphyrin, a process that, in the present systems, can be “switched on”, reversibly, by oxidation to the ferrocenium ion.

    Item Type: Article
    Keywords: Redox control; meso-Zinc(II) ferrocenylporphyrin; fluorescence switches;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 7982
    Identification Number: https://doi.org/10.1021/ic0703326
    Depositing User: Dr. Denise Rooney
    Date Deposited: 01 Mar 2017 16:03
    Journal or Publication Title: Inorganic Chemistry
    Publisher: American Chemical Society
    Refereed: Yes
    Funders: Enterprise Ireland (EI)
    URI:

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