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Rochford, Jonathan, Rooney, A. Denise and Pryce, Mary T. (2007) Redox control of meso-Zinc(II) ferrocenylporphyrin based fluorescence switches. Inorganic Chemistry, 46 (18). pp. 7247-7249. ISSN 0020-1669
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Abstract
The switching on and off of porphyrin fluorescence is achieved through the use of the ferrocene/ferrocenium redox couple. This approach makes use of the quenching of the porphyrin fluorescence by excited-state electron transfer from the ferrocene to the porphyrin, a process that, in the present systems, can be “switched on”, reversibly, by oxidation to the ferrocenium ion.
| Item Type: | Article |
|---|---|
| Keywords: | Redox control; meso-Zinc(II) ferrocenylporphyrin; fluorescence switches; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7982 |
| Identification Number: | 10.1021/ic0703326 |
| Depositing User: | Dr. Denise Rooney |
| Date Deposited: | 01 Mar 2017 16:03 |
| Journal or Publication Title: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| Refereed: | Yes |
| Funders: | Enterprise Ireland (EI) |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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