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    Copper(11) complex of a tridentate N-Donor ligand with unexpected Cu-H interaction


    McGinley, John and Creaven, Bernadette and Mahon, Mary and Moore, Ann-Marie (2006) Copper(11) complex of a tridentate N-Donor ligand with unexpected Cu-H interaction. Inorganic Chemistry Communications, 9. pp. 231-234.

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    Abstract

    The new pyridine–amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. Graphical abstract A new pyridine–amine ligand has been prepared and its reaction with copper perchlorate characterised. An interesting phenyl-H–Cu interaction was observed.

    Item Type: Article
    Keywords: Tridentate pyridine–amine ligand; Synthesis; Copper(II) complex; X-ray crystal structure;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Faculty of Science and Engineering > Research Institutes > Institute of Immunology
    Item ID: 924
    Depositing User: John McGinley
    Date Deposited: 13 Mar 2008
    Journal or Publication Title: Inorganic Chemistry Communications
    Publisher: Elsevier
    Refereed: Yes
    URI:

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