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McGinley, John, Creaven, Bernadette, Mahon, Mary and Moore, Ann-Marie (2006) Copper(11) complex of a tridentate N-Donor ligand with unexpected Cu-H interaction. Inorganic Chemistry Communications, 9. pp. 231-234.
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Abstract
The new pyridine�amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.
Graphical abstract
A new pyridine�amine ligand has been prepared and its reaction with copper perchlorate characterised. An interesting phenyl-H�Cu interaction was observed.
| Item Type: | Article |
|---|---|
| Keywords: | Tridentate pyridine�amine ligand; Synthesis; Copper(II) complex; X-ray crystal structure; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry Faculty of Science and Engineering > Research Institutes > Institute of Immunology |
| Item ID: | 924 |
| Depositing User: | John McGinley |
| Date Deposited: | 13 Mar 2008 |
| Journal or Publication Title: | Inorganic Chemistry Communications |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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