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    Encapsulated Dicopper(I): Kinetic or Thermodynamic Stabilization?

    Qin, Lu and McCann, Malachy and Nelson, Jane (1993) Encapsulated Dicopper(I): Kinetic or Thermodynamic Stabilization? Journal of Inorganic Biochemistry, 51. pp. 633-639. ISSN 0162-0134

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    Cyclic voltammetry of a series of air-stable dicopper(I.I) azacryptates indicates that some, including those with heterocyclic-N-donor spacers, are thermodynamically unstable towards oxidation by O2; in this case outer-sphere oxidation by Fc+ or Ag+ is readily achieved.

    Item Type: Article
    Keywords: Encapsulated; Dicopper(I); Kinetic; Thermodynamic; Stabilization;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 14512
    Depositing User: Dr. Malachy McCann
    Date Deposited: 04 Jun 2021 14:40
    Journal or Publication Title: Journal of Inorganic Biochemistry
    Publisher: Elsevier
    Refereed: Yes
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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