Devereux, Michael and McCann, Malachy and Casey, Michael T. and Curran, Martin and Ferguson, George and Cardin, Christine and Convery, Moira and Quillet, Valerie (1995) Binuclear and Polymeric Manganese (II) Salicylate Complexes: Synthesis, Crystal Structure and Catalytic Activity of [Mn2(Hsal)4(H2O)4] and [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n] (H2sal=salicylic acid, py=pyridine). Journal of the Chemical Society, Dalton Transactions, 1. pp. 771-776.

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Abstract

The two air-stable manganese(II) salicylate complexes [Mn2(Hsal)4(H2O)4] 1 and poymeric [Mn2(sal)2(Hsal)(H2O)(H3O)(py)4-2py}.,,] 2 (H2sal=salicylic acid and py=pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmetrically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the dis-proportionation of H2O2.

Item Type:	Article
Keywords:	Binuclear; Polymeric; Manganese (II); Salicylate Complexes; Synthesis; Crystal Structure; Catalytic; Activity; of [Mn2(Hsal)4(H2O)4]; [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n]; (H2sal=salicylic acid, py=pyridine);
Academic Unit:	Faculty of Science and Engineering > Chemistry
Item ID:	14513
Depositing User:	Dr. Malachy McCann
Date Deposited:	04 Jun 2021 14:57
Journal or Publication Title:	Journal of the Chemical Society, Dalton Transactions
Refereed:	Yes
URI:	Publisher
Use Licence:	This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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