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    Binuclear and Polymeric Manganese (II) Salicylate Complexes: Synthesis, Crystal Structure and Catalytic Activity of [Mn2(Hsal)4(H2O)4] and [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n] (H2sal=salicylic acid, py=pyridine)


    Devereux, Michael and McCann, Malachy and Casey, Michael T. and Curran, Martin and Ferguson, George and Cardin, Christine and Convery, Moira and Quillet, Valerie (1995) Binuclear and Polymeric Manganese (II) Salicylate Complexes: Synthesis, Crystal Structure and Catalytic Activity of [Mn2(Hsal)4(H2O)4] and [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n] (H2sal=salicylic acid, py=pyridine). Journal of the Chemical Society, Dalton Transactions, 1. pp. 771-776.

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    Abstract

    The two air-stable manganese(II) salicylate complexes [Mn2(Hsal)4(H2O)4] 1 and poymeric [Mn2(sal)2(Hsal)(H2O)(H3O)(py)4-2py}.,,] 2 (H2sal=salicylic acid and py=pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmetrically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the dis-proportionation of H2O2.

    Item Type: Article
    Keywords: Binuclear; Polymeric; Manganese (II); Salicylate Complexes; Synthesis; Crystal Structure; Catalytic; Activity; of [Mn2(Hsal)4(H2O)4]; [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n]; (H2sal=salicylic acid, py=pyridine);
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 14513
    Depositing User: Dr. Malachy McCann
    Date Deposited: 04 Jun 2021 14:57
    Journal or Publication Title: Journal of the Chemical Society, Dalton Transactions
    Refereed: Yes
    URI:

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