Devereux, Michael and McCann, Malachy and Casey, Michael T. and Curran, Martin and Ferguson, George and Cardin, Christine and Convery, Moira and Quillet, Valerie
(1995)
Binuclear and Polymeric Manganese (II) Salicylate Complexes: Synthesis, Crystal Structure and Catalytic Activity of [Mn2(Hsal)4(H2O)4] and [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n] (H2sal=salicylic acid, py=pyridine).
Journal of the Chemical Society, Dalton Transactions, 1.
pp. 771-776.
Abstract
The two air-stable manganese(II) salicylate complexes [Mn2(Hsal)4(H2O)4] 1 and poymeric [Mn2(sal)2(Hsal)(H2O)(H3O)(py)4-2py}.,,] 2 (H2sal=salicylic acid and py=pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmetrically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the dis-proportionation of H2O2.
Item Type: |
Article
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Keywords: |
Binuclear; Polymeric; Manganese (II); Salicylate Complexes; Synthesis; Crystal Structure; Catalytic; Activity; of [Mn2(Hsal)4(H2O)4]; [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n]; (H2sal=salicylic acid, py=pyridine); |
Academic Unit: |
Faculty of Science and Engineering > Chemistry |
Item ID: |
14513 |
Depositing User: |
Dr. Malachy McCann
|
Date Deposited: |
04 Jun 2021 14:57 |
Journal or Publication Title: |
Journal of the Chemical Society, Dalton Transactions |
Refereed: |
Yes |
URI: |
|
Use Licence: |
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