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Qin, Lei, Wright, James R., Lane, Jakob D. E., Berry, Stuart N., Elmes, Robert B. P. and Jolliffe, Katrina A. (2019) Receptors for sulfate that function across a wide pH range in mixed aqueous–DMSO media. Chemical Communications, 55 (82). pp. 12312-12315. ISSN 1359-7345
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Abstract
Water soluble squaramide macrocycles (MSQs) display high sulfate binding affinities in aqueous DMSO mixtures. The introduction of pyridine spacers into the macrocycles resulted in increased sulfate binding affinity in comparison to compounds with benzene spacers. [3]MSQ 6 was found to be a selective ligand for SO42− in highly competitive conditions and over a wide pH range (3.2–14).
| Item Type: | Article |
|---|---|
| Keywords: | Receptors; sulfate; function; wide pH range; mixed aqueous–DMSO; media; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry Faculty of Science and Engineering > Research Institutes > Human Health Institute |
| Item ID: | 16162 |
| Identification Number: | 10.1039/C9CC06812K |
| Depositing User: | Robert Elmes |
| Date Deposited: | 21 Jun 2022 11:44 |
| Journal or Publication Title: | Chemical Communications |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mural.maynoothuniversity.ie/id/eprint/16162 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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