Ambolikar, Arvind S. and Guin, Saurav K. (2020) Template‐free Electrosynthesis of Platinum Nano‐Cauliflowers for Catalysing Electron Transfer Reaction of Plutonium. Electroanalysis, 32 (11). pp. 2503-2510. ISSN 1040-0397

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Abstract

A coupled-oxido-reductive multiple-potentiostatic pulse strategy was developed to electrochemically prepare platinum-nano-cauliflowers (PtNCFs) on indium-tin-oxide (ITO) coated glass electrode. The mechanism of electrocrystallization was studied during the formation of PtNCFs on ITO. By virtue of that synthesis strategy, the PtNCFs/ITO surface could catalyse the quasi-reversible electron transfer reaction of plutonium (Pu) (IV)/(III) redox couple in aqueous sulphuric acid solution compared to bare ITO.

Item Type:	Article
Keywords:	Electrocatalysis; Electro crystallization; Platinumnano-cauliflowers; Heterogeneous electron transfer rate constant; Plutonium;
Academic Unit:	Faculty of Science and Engineering > Chemistry
Item ID:	16197
Identification Number:	https://doi.org/10.1002/elan.202060058
Depositing User:	Saurav Kumar Guin
Date Deposited:	29 Jun 2022 08:13
Journal or Publication Title:	Electroanalysis
Refereed:	Yes
URI:	Publisher
Use Licence:	This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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