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    Thermal Upgrade of Enzymatically Synthesized Aliphatic and Aromatic Oligoesters

    Comerford, James W. and Byrne, Fergal P. and Weinberger, Simone and Farmer, Thomas J. and Guebitz, Georg M. and Gardossi, Lucia and Pellis, Alessandro (2020) Thermal Upgrade of Enzymatically Synthesized Aliphatic and Aromatic Oligoesters. Materials, 13 (2). p. 368. ISSN 1996-1944

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    The enzymatic synthesis of polyesters in solventless systems is an environmentally friendly and sustainable method for synthetizing bio-derived materials. Despite the greenness of the technique, in most cases only short oligoesters are obtained, with limited practical applications or requiring further chemical processing for their elongation. In this work, we present a catalyst-free thermal upgrade of enzymatically synthesized oligoesters. Different aliphatic and aromatic oligoesters were synthesized using immobilized Candida antarctica lipase B (iCaLB) as the catalyst (70 ◦C, 24 h) yielding poly(1,4-butylene adipate) (PBA, Mw = 2200), poly(1,4-butylene isophthalate) (PBI, Mw = 1000), poly(1,4-butylene 2,5-furandicarboxylate) (PBF, Mw = 600), and poly(1,4-butylene 2,4-pyridinedicarboxylate) (PBP, Mw = 1000). These polyesters were successfully thermally treated to obtain an increase in Mw of 8.5, 2.6, 3.3, and 2.7 folds, respectively. This investigation focused on the most successful upgrade, poly(1,4-butylene adipate), then discussed the possible effect of di-ester monomers as compared to di-acids in the thermally driven polycondensation. The herein-described two-step synthesis method represents a practical and cost-effective way to synthesize higher-molecular-weight polymers without the use of toxic metal catalysts such as titanium(IV) tert-butoxide, tin(II) 2-ethylhexanoate, and in particular, antimony(IV) oxide. At the same time, the method allows for the extension of the number of reuses of the biocatalyst by preventing its exposure to extreme denaturating conditions.

    Item Type: Article
    Keywords: bio-based polyesters; enzymatic synthesis; polycondensation; thermal upgrade; metal-free synthesis; biocatalyzed process; solventless reactions;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 16697
    Identification Number:
    Depositing User: Fergal Byrne
    Date Deposited: 14 Nov 2022 15:09
    Journal or Publication Title: Materials
    Publisher: MDPI
    Refereed: Yes
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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