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    Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and Aldehydes

    Pezzati, Bernardo and Chellat, Mathieu F. and Murphy, John J. and Besnard, Céline and Reginato, Gianna and Stephens, John C. and Alexakis, Alexandre (2013) Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and Aldehydes. Organic Letters, 15 (12). pp. 2950-2953. ISSN 1523-7060

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    Asymmetric organocatalytic annulation of E/Z isomeric mixtures of bis(alkyl carboxylate)buta-1,3-dienes and aldehydes has been realized via enamine catalysis. In the presence of R,R-diphenyl-2-pyrrolidinemethanol trimethylsilyl ether, excellent stereo- and enantioselectivities were achieved for a broad spectrum of substrates.

    Item Type: Article
    Keywords: Organocatalytic Asymmetric Annulation; bis(alkyl carboxylate)buta-1; 3-dienes; aldehydes; enamine catalysis;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 7703
    Identification Number:
    Depositing User: Dr John Stephens
    Date Deposited: 10 Jan 2017 15:06
    Journal or Publication Title: Organic Letters
    Publisher: American Chemical Society
    Refereed: Yes
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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