Rochford, Jonathan and Rooney, A. Denise and Pryce, Mary T.
(2007)
Redox control of meso-Zinc(II) ferrocenylporphyrin based fluorescence switches.
Inorganic Chemistry, 46 (18).
pp. 7247-7249.
ISSN 0020-1669
Abstract
The switching on and off of porphyrin fluorescence is achieved through the use of the ferrocene/ferrocenium redox couple. This approach makes use of the quenching of the porphyrin fluorescence by excited-state electron transfer from the ferrocene to the porphyrin, a process that, in the present systems, can be “switched on”, reversibly, by oxidation to the ferrocenium ion.
| Item Type: |
Article
|
| Keywords: |
Redox control; meso-Zinc(II) ferrocenylporphyrin; fluorescence switches; |
| Academic Unit: |
Faculty of Science and Engineering > Chemistry |
| Item ID: |
7982 |
| Identification Number: |
https://doi.org/10.1021/ic0703326 |
| Depositing User: |
Dr. Denise Rooney
|
| Date Deposited: |
01 Mar 2017 16:03 |
| Journal or Publication Title: |
Inorganic Chemistry |
| Publisher: |
American Chemical Society |
| Refereed: |
Yes |
| Funders: |
Enterprise Ireland (EI) |
| URI: |
|
| Use Licence: |
This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available
here |
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