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Amir-Ebrahimi, Valia, Hamilton, James G., Nelson, Jane, Rooney, John J., Thompson, Jillian M., Beaumont, Andrew J., Rooney, A. Denise and Harding, Charles J. (1999) First evidence for radical anions in metathesis catalysis. Chemical Communications, 17. pp. 1621-1622. ISSN 1359-7345
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Abstract
The Grubbs’ catalyst, (PCy3)2RuCl2([double bond, length half m-dash]CHPh), generates persistent radical anions on treatment with π-acceptors such as p-benzoquinones and a remarkably wide range of dienes and even simple alkenes.
| Item Type: | Article |
|---|---|
| Keywords: | radical anions; metathesis catalysis; Grubbs’ catalyst; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 8019 |
| Depositing User: | Dr. Denise Rooney |
| Date Deposited: | 10 Mar 2017 15:37 |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemstry |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mural.maynoothuniversity.ie/id/eprint/8019 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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