Ahmed, Muhib, Devereux, Michael, McKee, Vickie, McCann, Malachy and Rooney, A. Denise (2019) (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand. Acta Crystallographica. Section E, Crystallographic Communications, 75. pp. 1224-1227. ISSN 2056-9890
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Abstract
Phenanthroline ligands are important metal-binding molecules which have been extensively researched for applications in both material science and medicinal chemistry. Azobenzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as molecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2·2CHCl3.
Item Type: | Article |
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Keywords: | crystal structure; diazo; phenanthroline; superconjugated ligand; |
Academic Unit: | Faculty of Science and Engineering > Chemistry |
Item ID: | 12585 |
Identification Number: | 10.1107/S205698901900954X |
Depositing User: | Dr. Denise Rooney |
Date Deposited: | 23 Mar 2020 12:09 |
Journal or Publication Title: | Acta Crystallographica. Section E, Crystallographic Communications |
Publisher: | International Union of Crystallography |
Refereed: | Yes |
Related URLs: | |
URI: | https://mural.maynoothuniversity.ie/id/eprint/12585 |
Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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