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Ambolikar, Arvind S. and Guin, Saurav K. (2020) Template‐free Electrosynthesis of Platinum Nano‐Cauliflowers for Catalysing Electron Transfer Reaction of Plutonium. Electroanalysis, 32 (11). pp. 2503-2510. ISSN 1040-0397
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Abstract
A coupled-oxido-reductive multiple-potentiostatic pulse strategy was developed to electrochemically prepare platinum-nano-cauliflowers (PtNCFs) on indium-tin-oxide (ITO) coated glass electrode. The mechanism of electrocrystallization was studied during the formation of PtNCFs on ITO. By virtue of that synthesis strategy, the PtNCFs/ITO surface could catalyse the quasi-reversible electron transfer reaction of plutonium (Pu) (IV)/(III) redox couple in aqueous sulphuric acid solution compared to bare ITO.
| Item Type: | Article |
|---|---|
| Keywords: | Electrocatalysis; Electro crystallization; Platinumnano-cauliflowers; Heterogeneous electron transfer rate constant; Plutonium; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 16197 |
| Identification Number: | 10.1002/elan.202060058 |
| Depositing User: | Saurav Kumar Guin |
| Date Deposited: | 29 Jun 2022 08:13 |
| Journal or Publication Title: | Electroanalysis |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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