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Pezzati, Bernardo, Chellat, Mathieu F., Murphy, John J., Besnard, Céline, Reginato, Gianna, Stephens, John C. and Alexakis, Alexandre (2013) Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and Aldehydes. Organic Letters, 15 (12). pp. 2950-2953. ISSN 1523-7060
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Abstract
Asymmetric organocatalytic annulation of E/Z isomeric mixtures of bis(alkyl carboxylate)buta-1,3-dienes and aldehydes has been realized via
enamine catalysis. In the presence of R,R-diphenyl-2-pyrrolidinemethanol trimethylsilyl ether, excellent stereo- and enantioselectivities were
achieved for a broad spectrum of substrates.
| Item Type: | Article |
|---|---|
| Keywords: | Organocatalytic Asymmetric Annulation; bis(alkyl carboxylate)buta-1; 3-dienes; aldehydes; enamine catalysis; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7703 |
| Identification Number: | 10.1021/ol401042b |
| Depositing User: | Dr John Stephens |
| Date Deposited: | 10 Jan 2017 15:06 |
| Journal or Publication Title: | Organic Letters |
| Publisher: | American Chemical Society |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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