Ahmed, Muhib and Devereux, Michael and McKee, Vickie and McCann, Malachy and Rooney, A. Denise (2019) (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand. Acta Crystallographica. Section E, Crystallographic Communications, 75. pp. 1224-1227. ISSN 2056-9890

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Abstract

Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2·2CHCl3.

Item Type:	Article
Keywords:	crystal structure; diazo; phenanthroline; superconjugated ligand;
Academic Unit:	Faculty of Science and Engineering > Chemistry
Item ID:	12585
Identification Number:	https://doi.org/10.1107/S205698901900954X
Depositing User:	Dr. Denise Rooney
Date Deposited:	23 Mar 2020 12:09
Journal or Publication Title:	Acta Crystallographica. Section E, Crystallographic Communications
Publisher:	International Union of Crystallography
Refereed:	Yes
URI:	Publisher
Use Licence:	This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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