MURAL - Maynooth University Research Archive Library

    (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand

    Ahmed, Muhib and Devereux, Michael and McKee, Vickie and McCann, Malachy and Rooney, A. Denise (2019) (E)-6,6'-(Diazene-1,2-di-yl)bis-(1,10-phenanthrolin-5-ol) tri-chloro-methane disolvate: a superconjugated ligand. Acta Crystallographica. Section E, Crystallographic Communications, 75. pp. 1224-1227. ISSN 2056-9890

    Download (522kB) | Preview

    Share your research

    Twitter Facebook LinkedIn GooglePlus Email more...

    Add this article to your Mendeley library


    Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2·2CHCl3.

    Item Type: Article
    Keywords: crystal structure; diazo; phenanthroline; superconjugated ligand;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 12585
    Identification Number:
    Depositing User: Dr. Denise Rooney
    Date Deposited: 23 Mar 2020 12:09
    Journal or Publication Title: Acta Crystallographica. Section E, Crystallographic Communications
    Publisher: International Union of Crystallography
    Refereed: Yes
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

    Repository Staff Only(login required)

    View Item Item control page


    Downloads per month over past year

    Origin of downloads