Joy, Sucheta and Krämer, Tobias and Paul, Nanda D. and Banerjee, Priyabrata and McGrady, John E. and Goswami, Sreebrata (2011) Isolation and Assessment of the Molecular and Electronic Structures of Azo-Anion-Radical Complexes of Chromium and Molybdenum. Experimental and Theoretical Characterization of Complete Electron-Transfer Series. Inorganic Chemistry, 50 (20). pp. 9993-10004. ISSN 0020-1669

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Abstract

The reaction of 3 equiv of the ligand 2-[(2-chlorophenyl)azo]pyridine (La) or 2-[(4-chlorophenyl)azo]pyridine (Lb) with 1 equiv of Cr(CO)6 or Mo(CO)6 in boiling n-octane afforded [Cr(La/b)3]0 (1a and 1b) and [Mo(La/b)3]0 (2a and 2b). The chemical oxidation reaction of these neutral complexes with I2 in CH2Cl2 provided access to air-stable one-electron-oxidized species as their triiodide (I3–) salts. The electronic structures of chromium and molybdenum centers coordinated by the three redox noninnocent ligands La/b along with their redox partners have been elucidated by using a host of physical methods: X-ray crystallography, magnetic susceptibility measurements, nuclear magnetic resonance, cyclic voltammetry, absorption spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory. The four representative complexes, 1a, [1a]I3, 2a, and [2a]I3, have been characterized by X-ray crystallography. The results indicate a predominant azo-anion-radical description of the ligands in the neutral chromium(III) species, [CrIII(L•–)3], affording a singlet ground state through strong metal–ligand antiferromagnetic coupling. All of the electrochemical processes are ligand-based; i.e., the half-filled (t2g)3 set of the CrIII d3 ion remains unchanged throughout. The description of the molybdenum analogue is less clear-cut because mixing between metal- and ligand-based orbitals is more significant. On the basis of variations in net spin densities and orbital compositions, we argue that the oxidation events are again primarily ligand-based, although the electron density at the molybdenum center is clearly more variable than that at the chromium center in the corresponding series [1a]+, 1a, and [1a]−.

Item Type:	Article
Keywords:	Isolation; Assessment; Molecular; Electronic Structures; Azo-Anion-Radical Complexes; Chromium; Molybdenum; Experimental; Theoretical Characterization; Complete Electron-Transfer Series;
Academic Unit:	Faculty of Science and Engineering > Computer Science Faculty of Science and Engineering > Research Institutes > Hamilton Institute
Item ID:	15521
Identification Number:	https://doi.org/10.1021/ic200708c
Depositing User:	Tobias Kraemer
Date Deposited:	16 Feb 2022 13:09
Journal or Publication Title:	Inorganic Chemistry
Publisher:	American Chemical Society
Refereed:	Yes
URI:	Publisher
Use Licence:	This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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