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    Template‐free Electrosynthesis of Platinum Nano‐Cauliflowers for Catalysing Electron Transfer Reaction of Plutonium


    Ambolikar, Arvind S. and Guin, Saurav K. (2020) Template‐free Electrosynthesis of Platinum Nano‐Cauliflowers for Catalysing Electron Transfer Reaction of Plutonium. Electroanalysis, 32 (11). pp. 2503-2510. ISSN 1040-0397

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    Abstract

    A coupled-oxido-reductive multiple-potentiostatic pulse strategy was developed to electrochemically prepare platinum-nano-cauliflowers (PtNCFs) on indium-tin-oxide (ITO) coated glass electrode. The mechanism of electrocrystallization was studied during the formation of PtNCFs on ITO. By virtue of that synthesis strategy, the PtNCFs/ITO surface could catalyse the quasi-reversible electron transfer reaction of plutonium (Pu) (IV)/(III) redox couple in aqueous sulphuric acid solution compared to bare ITO.

    Item Type: Article
    Keywords: Electrocatalysis; Electro crystallization; Platinumnano-cauliflowers; Heterogeneous electron transfer rate constant; Plutonium;
    Academic Unit: Faculty of Science and Engineering > Chemistry
    Item ID: 16197
    Identification Number: https://doi.org/10.1002/elan.202060058
    Depositing User: Saurav Kumar Guin
    Date Deposited: 29 Jun 2022 08:13
    Journal or Publication Title: Electroanalysis
    Refereed: Yes
    URI:
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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