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Zaher, Hasna, Ashley, Andrew E, Irwin, Mark, Thompson, Amber L., Gutmann, Matthias, Krämer, Tobias and O'Hare, Dermot (2013) Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H...H–[TMP]. Chemical Communications, 49. pp. 9755-9757. ISSN 1364-548X
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Abstract
The product of the intermolecular ‘frustrated Lewis pair’ (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H⋯H) bond within a hydrogenated FLP system.
| Item Type: | Article |
|---|---|
| Keywords: | Structural; theoretical studies; intermolecular; dihydrogen; bonding; [(C6F5)2(C6Cl5)B]–H...H–[TMP]; |
| Academic Unit: | Faculty of Science and Engineering > Computer Science Faculty of Science and Engineering > Research Institutes > Hamilton Institute |
| Item ID: | 15507 |
| Identification Number: | 10.1039/c3cc45889 |
| Depositing User: | Tobias Kraemer |
| Date Deposited: | 15 Feb 2022 15:05 |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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