We show that after forming a connected sum with a homotopy sphere, all (2j-1)-connected 2j-parallelisable manifolds in dimension 4j+1, j > 0, can be equipped with Riemannian metrics of 2-positive Ricci curvature. When j=1 we extend the above to certain classes of simply-connected non-spin 5-manifolds. The condition of 2-positive Ricci curvature is defined to mean that the sum of the two smallest eigenvalues of the Ricci tensor is positive at every point. This result is a counterpart to a previous result of the authors concerning the existence of positive Ricci curvature on highly connected manifolds in dimensions 4j-1 for j > 1, and in dimensions 4j+1 for j > 0 with torsion-free cohomology. A key technical innovation involves performing surgery on links of spheres within 2-positive Ricci curvature.