Share and Export
Share and Export
Raza, Asif, Javannikkhah, Sousa, Croitor, Lilia, Attallah, Ahmed Gamal, Hirschmann, Eric, Vandichel, Matthias and Mukherjee, Soumya (2025) An ionic ultramicroporous polymer with engineered nanopores enables enhanced acetylene/carbon dioxide separation. Chemical Communications, 61 (35). pp. 6466-6469. ISSN 1359-7345
Preview
Available under License Creative Commons Attribution Non-commercial Share Alike.
Download (1MB) | Preview
Abstract
A nanopore engineering approach enhances acetylene (C 2 H 2 ) over carbon dioxide (CO 2 ) selectivity in ionic ultramicroporous polymers (IUPs), an understudied class of sorbents. Extending the cationic arm of a prototypical IUP nearly doubles its C 2 H 2 /CO 2 selectivity from 4.9 to 8.5 (at 298 K, 1 bar), underpinned by further observations from dynamic separation experiments and bespoke computational insights.
| Item Type: | Article |
|---|---|
| Keywords: | ionic ultramicroporous polymer; engineered; nanopores; acetylene/carbon dioxide; |
| Academic Unit: | Faculty of Science & Engineering > Chemistry Faculty of Science & Engineering > Research Institutes > Hamilton Institute Faculty of Science & Engineering > Research Institutes > Human Health Institute |
| Item ID: | 21498 |
| Identification Number: | 10.1039/D5CC01092F |
| Depositing User: | Sousa Javannikkhah |
| Date Deposited: | 30 Apr 2026 16:00 |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| Refereed: | Yes |
| Related URLs: | |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
Downloads
Downloads per month over past year
Origin of downloads
Altmetric Badge
Repository Staff Only (login required)
- Item control page
