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    Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity


    Dutta, Subhajit, Mukherjee, Soumya, Javannikkhah, Sousa, Qazvini, Omid T., Dam, Gourab K., Vandichel, Matthias, Mandal, Tarak Nath and Ghosh, Sujit K. (2024) Hemilabile Binding of Acetylene in an Amide-Rich Ultramicroporous MOF Enables Strong Acetylene Selectivity. Inorganic Chemistry, 63 (27). pp. 12404-12408. ISSN 0020-1669

    Abstract

    Thanks to a hemilabile amide-based binding site, a previously unreported amide-functionalized metal–organic framework (MOF) exhibits high acetylene affinity over ethylene, methane, and carbon dioxide, three-in-one.
    Item Type: Article
    Keywords: Hemilabile Binding; Acetylene; Amide-Rich Ultramicroporous; MOF; Acetylene Selectivity;
    Academic Unit: Faculty of Science & Engineering > Chemistry
    Faculty of Science & Engineering > Research Institutes > Hamilton Institute
    Faculty of Science & Engineering > Research Institutes > Human Health Institute
    Item ID: 21499
    Identification Number: 10.1021/acs.inorgchem.4c01933
    Depositing User: Sousa Javannikkhah
    Date Deposited: 30 Apr 2026 16:07
    Journal or Publication Title: Inorganic Chemistry
    Publisher: American Chemical Society
    Refereed: Yes
    Related URLs:
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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