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    Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H...H–[TMP]

    Zaher, Hasna and Ashley, Andrew E and Irwin, Mark and Thompson, Amber L. and Gutmann, Matthias and Krämer, Tobias and O'Hare, Dermot (2013) Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H...H–[TMP]. Chemical Communications, 49. pp. 9755-9757. ISSN 1364-548X

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    The product of the intermolecular ‘frustrated Lewis pair’ (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H⋯H) bond within a hydrogenated FLP system.

    Item Type: Article
    Keywords: Structural; theoretical studies; intermolecular; dihydrogen; bonding; [(C6F5)2(C6Cl5)B]–H...H–[TMP];
    Academic Unit: Faculty of Science and Engineering > Computer Science
    Faculty of Science and Engineering > Research Institutes > Hamilton Institute
    Item ID: 15507
    Identification Number:
    Depositing User: Tobias Kraemer
    Date Deposited: 15 Feb 2022 15:05
    Journal or Publication Title: Chemical Communications
    Publisher: Royal Society of Chemistry
    Refereed: Yes
    Use Licence: This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here

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