Article

Wang, Qingyang and Manzano, Richard A. and Tinnermann, Hendrik and Sung, Simon and Leforestier, Baptiste and Krämer, Tobias and Young, Rowan D. (2021) Access to and Reactivity of Fe 0 , Fe −I , Fe I , and Fe II PC carbene P Pincer Complexes. Angewandte Chemie, 133 (33). pp. 18316-18325. ISSN 0044-8249

Falconer, Rosalyn L. and Byrne, Keelan M. and Nichol, Gary S. and Krämer, Tobias and Cowley, Michael J. (2021) Reversible Dissociation of a Dialumene**. Angewandte Chemie International Edition, 60 (46). pp. 24702-24708. ISSN 1433-7851

Bukvic, Alexander J. and Burnage, Arron L. and Tizzard, Graham J. and Martínez-Martínez, Antonio J. and McKay, Alasdair I. and Rees, Nicholas H. and Tegner, Bengt E. and Krämer, Tobias and Fish, Heather and Warren, Mark R. and Coles, Simon J. and Macgregor, Stuart A. and Weller, Andrew S. (2021) A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane. Journal of the American Chemical Society, 143 (13). pp. 5106-5120. ISSN 0002-7863

Quek, Sebastian Y. and Debnath, Suman and Laxmi, Shoba and van Gastel, Maurice and Krämer, Tobias and England, Jason (2021) Sterically Stabilized End-On Superoxocopper(II) Complexes and Mechanistic Insights into Their Reactivity with O–H, N–H, and C–H Substrates. Journal of the American Chemical Society, 143 (47). pp. 19731-19747. ISSN 0002-7863

Idelson, Celia and Webster, Leah and Krämer, Tobias and Chadwick, F. Mark (2020) Asymmetric bis-PNP pincer complexes of zirconium and hafnium – a measure of hemilability. Dalton Transactions, 49 (46). pp. 16653-16656. ISSN 1477-9226

Coughlin, Omar and Krämer, Tobias and Benjamin, Sophie L. (2020) Diverse structure and reactivity of pentamethylcyclopentadienyl antimony(iii) cations. Dalton Transactions, 49 (6). pp. 1726-1730. ISSN 1477-9226

Kynman, Amy E. and Lau, Samantha and Dowd, Sean O. and Krämer, Tobias and Chaplin, Adrian B. (2020) Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex. European Journal of Inorganic Chemistry, 2020 (41). pp. 3899-3906. ISSN 1434-1948

Martin, Harlei and Somers, Tara and Dwyer, Mathew and Robson, Ryan and Pfeffer, Frederick M. and Bjornsson, Ragnar and Krämer, Tobias and Kavanagh, Kevin and Velasco-Torrijos, Trinidad (2020) Scaffold diversity for enhanced activity of glycosylated inhibitors of fungal adhesion. RSC Medicinal Chemistry, 11 (12). pp. 1386-1401. ISSN 2632-8682

Brouillet, Etienne V. and Kennedy, Alan R. and Krämer, Tobias and Mulvey, Robert E. and Robertson, Stuart D. and Stewart, Alexander and Towie, Stephen (2020) Synthesis, Structure, and DFT Analysis of the THF Solvate of 2‐Picolyllithium: A 2‐Picolyllithium Solvate with Significant Carbanionic Character. Zeitschrift für anorganische und allgemeine Chemie, 646 (13). pp. 726-733. ISSN 0044-2313

Storey, Caroline M and Kalpokas, Audrius and Gyton, Matthew R and Krämer, Tobias and Chaplin, Adrian B (2020) A shape changing tandem Rh(CNC) catalyst: Preparation of bicyclo[4.2.0]octa- 1,5,7-trienes from terminal aryl alkynes. Chemical Science, 11 (8). pp. 2017-2304. ISSN 2041-6539

Storey, Caroline M. and Kalpokas, Audrius and Gyton, Matthew R. and Krämer, Tobias and Chaplin, Adrian B. (2020) A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes. Chemical Science, 11 (8). pp. 2051-2057. ISSN 2041-6520

Doyle, Amanda A. and Krämer, Tobias and Kavanagh, Kevin and Stephens, John C. (2019) Cinnamaldehydes: Synthesis, antibacterial evaluation, and the effect of molecular structure on antibacterial activity. Results in Chemistry, 1 (100013). ISSN 2211-7156

Sung, Simon and Tinnermann, Hendrik and Krämer, Tobias and Young, Rowan D. (2019) Direct oxide transfer from an η2-keto ligand to generate a cobalt PCcarbeneP(O) pincer complex. Dalton Transactions, 48 (27). pp. 9920-9924. ISSN 1477-9226

Krämer, Tobias and Tuna, Floriana and Pike, Sebastian D. (2019) Photo-redox reactivity of titanium-oxo clusters: Mechanistic insight into a two-electron intramolecular process, and structural characterisation of mixed-valent Ti(iii)/Ti(iv) products. Chemical Science, 10 (28). pp. 6886-6898. ISSN 2041-6539

Tennant, Mat and Chew, Siao Chien and Krämer, Tobias and Mai, Nathalie and McAteer, Daniel and Pons, Jean-Francois (2019) Practical Colorimetry of 3-Nitro-1,2,4-Triazol-5-One. Propellants, Explosives, Pyrotechnics, 44. pp. 198-202. ISSN 0721-3115

Marchetti, Luke A. and Mao, Nan and Krämer, Tobias and Kitchen, Jonathan A. and Elmes, Robert B.P. (2018) A long wavelength colourimetric chemosensor for fluoride. Supramolecular Chemistry, 30 (9). pp. 795-805. ISSN 1061-0278

McKay, Alasdair I. and Martinez-Martinez, Antonio J. and Griffiths, Hannah and Rees, Nichollas H. and Waters, Jordan B and Weller, Andrew S. and Krämer, Tobias and Macgregor, Stuart A. (2018) Controlling Structure and Reactivity in Cationic Solid-State Molecular Organometallic Systems Using Anion Templating. Organometallics, 37. pp. 3524-3532. ISSN 0276-7333

Jolleys, Andrew and Lake, Benjamin R. M. and Krämer, Tobias and Benjamin, Sophie (2018) A Five-Membered PdSbn Coordination Series. Organometallics, 37. pp. 3854-3862. ISSN 0276-7333

Sung, Simon and Wang, Qingyang and Krämer, Tobias and Young, Rowan D (2018) Synthesis and reactivity of a PCcarbeneP cobalt(I) complex: the missing link in the cobalt PXP pincer series (X = B, C, N). Chemical Science, 9. pp. 8234-8241. ISSN 2041-6539

Sung, Simon and Joachim, Timothy and Krämer, Tobias and Young, Rowan D. (2017) Protonolysis of an α-Hydroxyl Ligand for the Generation of a PCcarbeneP Pincer Complex and Subsequent Reactivity Studies. Organometallics, 36 (16). pp. 3117-3124. ISSN 0276-7333

Sung, Simon and Boon, Jie Kang and Lee, Johnathan J.C. and Rajabi, Nasir A. and Macgregor, Stuart A. and Krämer, Tobias and Young, Rowan D. (2017) Convergent (De)Hydrogenative Pathways via a Rhodium α-Hydroxylalkyl Complex. Organometallics, 36 (8). pp. 1609-1617. ISSN 0276-7333

McKay, Alasdair I. and Krämer, Tobias and Rees, Nichollas H. and Thompson, Amber L. and Christensen, Kirsten E. and Macgregor, Stuart A. and Weller, Andrew S. (2017) Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]. Organometallics, 36 (1). pp. 22-25. ISSN 0276-7333

Riley, Laura E. and Krämer, Tobias and McMullin, Claire L. and Ellis, David and Rosair, Georgina M. and Sivaev, Igor B. and Welch, Alan J. (2017) Large, weakly basic bis(carboranyl)phosphines:an experimental and computational study. Dalton Transactions, 16 (46). pp. 5218-5228. ISSN 1477-9226

Chadwick, Mark and McKay, Alasdair I. and Martinez-Martinez, Antonio J. and Rees, Nichollas H. and Krämer, Tobias and Mcgregor, Stuart A. and Weller, Andrew S. (2017) Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates. Chemical Science, 8. pp. 6014-6029. ISSN 2041-6539

Benjamin, Sophie and Krämer, Tobias and Levason, William and Light, Mark E and Macgregor, Stuart A. and Reid, Gillian (2016) [Pd4(μ3‑SbMe3)4(SbMe3)4]: A Pd(0) Tetrahedron with μ3‑Bridging Trimethylantimony Ligands. Journal of the American Chemical Society, 138 (22). A-D. ISSN 0002-7863

Chadwick, Mark and Rees, Nichollas H. and Weller, Andrew S. and Krämer, Tobias and Iannuzzi, Marcella and Macgregor, Stuart A. (2016) A Rhodium–Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques. Angewandte Chemie - International Edition, 55 (11). pp. 3677-3681. ISSN 0044-8249

Bachmeier, Andreas and Esselborn, Julian and Hexter, Suzannah V. and Krämer, Tobias and Klein, Kathrin and Happe, Thomas and McGrady, John E. and Myers, William K. and Armstrong, Fraser A. (2015) How Formaldehyde Inhibits Hydrogen Evolution by [FeFe]-Hydrogenases: Determination by13C ENDOR of Direct Fe–C Coordination and Order of Electron and Proton Transfers. Journal of the American Chemical Society, 137 (16). pp. 5381-5389. ISSN 0002-7863

Ogata, Hideaki and Krämer, Tobias and Wang, Hongxin and Schilter, David and Pelmenschikov, Vladimir and van Gastel, Maurice and Neese, Frank and Rauchfuss, Thomas B. and Gee, Leland B. and Scott, Aubrey D. and Yoda, Yoshitaka and Tanaka, Yoshihito and Lubitz, Wolfgang and Cramer, Stephen P. (2015) Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy. Nature Communications, 6 (1). ISSN 2041-1723

Pike, Sebastian D. and Chadwick, Mark and Rees, Nichollas H. and Scott, Mark P and Weller, Andrew S. and Krämer, Tobias and Macgregor, Stuart A. (2015) Solid-State Synthesis and Characterization of σ-Alkane Complexes, [Rh(L2)(η2,η2-C7H12)][BArF4] (L2 = Bidentate Chelating Phosphine). Journal of the American Chemical Society, 137 (2). pp. 820-833. ISSN 0002-7863

Pike, Sebastian D. and Krämer, Tobias and Rees, Nichollas H. and Macgregor, Stuart A. and Weller, Andrew S. (2015) Stoichiometric and Catalytic Solid−Gas Reactivity of Rhodium Bis-phosphine Complexes. Organometallics, 34 (8). pp. 1487-1497. ISSN 0276-7333

Klein, Eric L. and Belaidi, Abdel Ali and Raitsimring, Arnold M. and Davis, Amanda C. and Krämer, Tobias and Astashkin, Andrei V. and Neese, Frank and Schwarz, Günter and Enemark, John H. (2014) Pulsed Electron Paramagnetic Resonance Spectroscopy of 33S-Labeled Molybdenum Cofactor in Catalytically Active Bioengineered Sulfite Oxidase. Inorganic Chemistry, 53 (2). pp. 961-971. ISSN 0020-1669

Ghosh, Pradip and Samanta, Subhas and Roy, Suman K and Joy, Sucheta and Krämer, Tobias and McGrady, John E. and Goswami, Sreebrata (2013) Redox Noninnocence in Coordinated 2-(Arylazo)pyridines: Steric Control of Ligand-Based Redox Processes in Cobalt Complexes. Inorganic Chemistry, 52 (24). pp. 14040-14049. ISSN 0020-1669

Zaher, Hasna and Ashley, Andrew E and Irwin, Mark and Thompson, Amber L. and Gutmann, Matthias and Krämer, Tobias and O'Hare, Dermot (2013) Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]–H...H–[TMP]. Chemical Communications, 49. pp. 9755-9757. ISSN 1364-548X

Krämer, Tobias and Duckworth, Jack C A and Ingram, Matthew D and Zhou, Binbin and McGrady, John E. and Goicoechea, Jose M. (2013) Structural trends in ten-vertex endohedral clusters, M@E10 and the synthesis of a new member of the family, [Fe@Sn10]3−. Dalton Transactions, 42. pp. 12120-12129. ISSN 1477-9226

Krämer, Tobias and Kampa, Mario and Lubitz, Wolfgang and van Gastel, Maurice and Neese, Frank (2013) Theoretical spectroscopy of the Ni(II) intermediate states in the catalytic cycle and the activation of [NiFe] hydrogenases. ChemBioChem, 14 (14). pp. 1898-1905. ISSN 1439-4227

Weber, Katharina and Krämer, Tobias and Shafaat, Hannah S. and Weyhermüller, Thomas and Bill, Eckhard and van Gastel, Maurice and Neese, Frank and Lubitz, Wolfgang (2012) A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation. Journal of the American Chemical Society, 134 (51). pp. 20745-20755. ISSN 0002-7863

Irwin, Mark and Doyle, Laurence R. and Krämer, Tobias and Herchel, Radovan and McGrady, John E. and Goicoechea, Jose M. (2012) A Homologous Series of First-Row Transition-Metal Complexes of 2,2′-Bipyridine and their Ligand Radical Derivatives: Trends in Structure, Magnetism, and Bonding. Inorganic Chemistry, 51 (22). pp. 12301-12312. ISSN 0020-1669

Foster, Carina E. and Krämer, Tobias and Wait, Annemarie F. and Parkin, Alison and Jennings, David P. and Happe, Thomas and McGrady, John E. and Armstrong, Fraser A. (2012) Inhibition of [FeFe]-Hydrogenases by Formaldehyde and Wider Mechanistic Implications for Biohydrogen Activation. Journal of the American Chemical Society, 134 (17). pp. 7553-7557. ISSN 0002-7863

Sparkes, Hazel A. and Krämer, Tobias and Brayshaw, Simon K. and Green, Jennifer C. and Weller, Andrew S. and Howard, Judith A. K. (2011) Experimental charge density study into C–C σ-interactions in a Binor-S rhodium complex. Dalton Transactions, 40 (40). pp. 10708-10718. ISSN 1477-9226

Zhou, Binbin and Krämer, Tobias and Thompson, Amber L. and McGrady, John E. and Goicoechea, Jose M. (2011) A Highly Distorted Open-Shell Endohedral Zintl Cluster: [Mn@Pb12]3–. Inorganic Chemistry, 50 (17). pp. 8028-8037. ISSN 0020-1669

Joy, Sucheta and Krämer, Tobias and Paul, Nanda D. and Banerjee, Priyabrata and McGrady, John E. and Goswami, Sreebrata (2011) Isolation and Assessment of the Molecular and Electronic Structures of Azo-Anion-Radical Complexes of Chromium and Molybdenum. Experimental and Theoretical Characterization of Complete Electron-Transfer Series. Inorganic Chemistry, 50 (20). pp. 9993-10004. ISSN 0020-1669

Irwin, Mark and Krämer, Tobias and McGrady, John E. and Goicoechea, Jose M. (2011) On the Structural and Electronic Properties of [Zn2(4,4′-bipyridine)(mes)4]n− (n = 0–2), a Homologous Series of Bimetallic Complexes Bridged by Neutral, Anionic, and Dianionic 4,4′-Bipyridine. Inorganic Chemistry, 50 (11). pp. 5006-5014. ISSN 0020-1669

Vidovic, Dragoslav and Addy, David A. and Krämer, Tobias and McGrady, John and Aldridge, Simon (2011) Probing the Intrinisic Structure and Dynamics of Aminoborane Coordination at Late Transition Metal Centers: Mono(σ-BH) Binding in [CpRu(PR3)2(H2BNCy2)]+. Journal of the American Chemical Society, 133 (22). pp. 8494-8497. ISSN 0002-7863

Ashley, Andrew E. and Herrington, Thomas J. and Wildgoose, Gregory G. and Zaher, Hasna and Thompson, Amber L. and Rees, Nicholas H. and Krämer, Tobias and O’Hare, Dermot (2011) Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C6F5)3–n(C6Cl5)n (n = 1–3). Journal of the American Chemical Society, 133 (37). pp. 14727-14740. ISSN 0002-7863

Irwin, Mark and Jenkins, Rhiannon K. and Denning, Mark S. and Krämer, Tobias and Grandjean, Fernande and Long, Gary J. and Herchel, Radovan and McGrady, John E. and Goicoechea, Jose M. (2010) Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2′-bipyridine)(mes)2 and [FeII(2,2′-bipyridine)(mes)2]−, a Complex Containing a 2,2′-Bipyridyl Radical Anion. Inorganic Chemistry, 49 (13). pp. 6160-6171. ISSN 0020-1669

Henschel, Henning and Krämer, Tobias and Lankau, Timm (2006) (H2O)10 and (H2O)12 on a Virtual Metal Surface: The Growth of Ice. Langmuir, 22 (26). pp. 10942-10950. ISSN 0743-7463